It will not trigger on itself going to the graveyard, or on any other cards going to the graveyard at the same time. This means that neither itself nor other cards put into the graveyard at the same time as it will get exiled.
04-10-2004
wotc
If spell is used to destroy Planar Void, it goes to the graveyard, then the spell goes to the graveyard. The spell is not exiled, as Planar Void was not on the battlefield when it was put into the graveyard.
04-10-2004
wotc
The card does go to the graveyard before it is exiled, so other triggered abilities will trigger on the card going to the graveyard.
Random a card of Magic: The Gathering (MTG), but you can also roll the D20 dice, random a Planeswalker, have fun with the random rules and more.